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The provenance of sandstones deposited in the late Paleozoic Tepuel-Genoa Basin is analyzed in this paper. Five sections were sampled in Esquel, Sierra de Tepuel, Sierra de Tecka, El Molle, and Río Genoa areas for petrographic and geochemical studies. The sandstones in the Tepuel-Genoa Basin are dominated by feldspathic litharenites and litharenites, showing lithic fragments of volcanic and sedimentary rocks in the Valle Chico Formation and medium-to high-grade metamorphic rock clasts in the rest of the units. Detrital modes of seventy-five sandstones samples from the Valle Chico, Pampa de Tepuel, Moj´on de Hierro, and Río Genoa formations were counted and analyzed. Seven modal components have discriminant value for identifying provenance areas (Qm, Qi, Lv, Lmm-h, Lm-Lp, Lm, Qpm). These modal components allow identification of three petrofacies: 1. Quartzose-lithic (Qm69Lv2Lm29), 2. Quartzose (Qm89Lv4Lm7) and 3. Volcanic-sedimentary (Qm60Lv38Lm1). The quartzose-lithic petrofacies is mainly composed of monocrystalline quartz, medium- and high-grade metamorphic clasts and polycrystalline quartz with cataclastic texture, this assemblage is interpreted as being derived from the crystalline rocks that form the Deseado Massif. The quartzose petrofacies is composed of monocrystalline quartz with scarce contributions of metamorphic clasts and traces of volcanic fragments; the provenance area is ascribed to sedimentary terrains, which most likely covered part of the Deseado Massif. The volcanic-sedimentary petrofacies is comprised of volcanic (acidic and intermediate rocks) and sedimentary (sandstone and mudstone) clasts, with discrete amounts of quartz grains with idiomorph shapes and embayments. This assemblage may correspond to material supply from the Devonian-Early Carboniferous accretionary complex developed in Chile or the unroofing of the western volcanic arc located in the central part of Patagonia. The validity of the three defined petrofacies was evaluated using Principal Component Analysis and triangular compositional diagrams; both methods show good separation and lack of overlap between the three petrofacies. Major (Si, Al, Fe, Na, K) and trace-REE elements (Zr, Th, Sc, Hf) were used to improve the petrographic information. The relation SiO2 against K2O/Na2O indicates that the Pampa de Tepuel and the Moj´on de Hierro formations correspond to a passive margin, while the Valle Chico and Río Genoa formations represent different types of active continental margins. The Th/Sc and Zr/Sc ratios and the Th-Hf-Co distributions indicate that the sandstones of the Tepuel Group were formed from rocks compatibles with the average composition of the upper continental crust. 

The timing and geographic distribution of glaciers in high-latitude southern Gondwana during the Late Paleozoic Ice Age remain poorly constrained, ultimately precluding our ability to estimate ice volume and associated climate teleconnections and feedbacks during Earth's penultimate icehouse. Current aerial extents of glaciers, constrained by sedimentary flow directions, near exclusively infer paleo-glaciation to be highland-driven and may underestimate potential ice sources in continental regions from which ice sheets may have emanated. Here, we report new U-Pb ages and Hf isotope compositions of detrital zircons recovered from diamictites in two key mid- to high-latitude Gondwanan basins (Paraná, Brazil and Tepuel, Argentine Patagonia). The results indicate regional sediment sources for both basins during the early period of late Paleozoic glaciation evolving into more distal sources during the final deglaciation along southern and western Gondwana. Similar age sediment sourced from diamictites in the Congo Basin, that require an ice center in eastern Africa suggest the possibility of a large ice sheet in this area of Africa proximal to the Carboniferous-Permian boundary, which may have sourced sediments to the Paraná Basin. An inferred distal southern source of glacial sediment for the Tepuel Basin argues for the presence of an ice sheet(s) in the Ellsworth Block of Antarctica towards the end of the glaciation history in Patagonia. These findings indicate an evolution during the Late Paleozoic Ice Age from proximally to extrabasinally sourced sediment reflecting continental-scale glaciation and subsequent drainage from the Windhoek Highlands, Ellsworth Block and an east African source in west-central Gondwana. Coincidence with a long-term fall in atmospheric pCO2 during the Pennsylvanian to a minimum across the Carboniferous-Permian boundary and a subsequent rise in the early Permian suggests a primary CO2-driver for deglaciation in the Paraná Basin. Additional boundary conditions including availability of moisture and paleogeography likely further contributed to the timing of nucleation, growth and demise of these Gondwanan glaciers.